As a thin material with a lamellar structure, graphene oxide (GO) may extend the already superior tribological properties of ferrofluids. For this purpose, magnetic Fe3O4 nanoparticles were fabricated on the GO surface with different compositions by the co-precipitation method. Then, the GO-Fe3O4 nanohybrids coated with a surfactant were dispersed in paraffin oil to achieve stable ferrofluids. The tribological results demonstrated that compared with paraffin oil, friction coefficient reduced by 19.4% and 25.8–35.5% when lubricated with ferrofluids containing 0.5 wt% of Fe3O4 nanoparticle and GO-Fe3O4 nanohybrids, respectively. The results also indicated that nanohybrids with the higher content of GO exhibited better lubrication behaviors. It can be concluded that the introduction of GO helps to further promote the lubricity of traditional Fe3O4-based ferrofluids. The excellent tribological behaviors of GO-Fe3O4-based ferrofluids were ascribed to the triboflim and the synergistic effects of GO and Fe3O4.

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